The Brattleboro officers were investigating whether 28-year-old Todd Koshinsky had violated conditions of his release from a previous stalking charge on Thursday when police say he became combative.
They say Koshinsky picked up a large brick and tried to hit the two officers. They say he also punched the officers.
Koshinsky and one of the officers were treated for injuries.
Koshinsky is charged with multiple counts of aggravated assault on a police officer, simple assault on a police officer, resisting arrest and violating conditions of release.
He's being held on $50,000 bail and is scheduled to appear in Windham Court on Friday.